Issue 8, 2016

Synthesis of digermylene-stabilized linear tetraboronate and boroxine

Abstract

Two newly discovered linear compounds tetraboronate and boroxine stabilized by digermylene are reported, which feature a B4O5 chain and a B3O3 ring, respectively. DFT calculations reveal that not only can digermylene stabilize the electron-deficient boron centers, but also increase the energies of the LUMOs of the boron moiety. Our results provide a hint for the development of boronate covalent organic frameworks.

Graphical abstract: Synthesis of digermylene-stabilized linear tetraboronate and boroxine

Supplementary files

Article information

Article type
Communication
Submitted
10 Nov 2015
Accepted
13 Nov 2015
First published
13 Nov 2015

Chem. Commun., 2016,52, 1582-1585

Synthesis of digermylene-stabilized linear tetraboronate and boroxine

Y. Wu, L. L. Liu, J. Su, K. Yan, J. Zhu and Y. Zhao, Chem. Commun., 2016, 52, 1582 DOI: 10.1039/C5CC09330A

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