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Issue 28, 2015
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Modulation of (non)linear optical properties in tripodal molecules by variation of the peripheral cyano acceptor moieties and the π-spacer

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Abstract

A series of twelve tripodal push-pull molecules with a central triphenylamine donor and peripheral cyano substituted acceptors has been prepared. These molecules possess systematically altered π-linkers as well as cyano acceptors. Based on the experimental properties measured by differential scanning calorimetry, electrochemistry, one and two photon absorption/emission spectroscopy, supported by the DFT calculations, thorough structure–property relationships were elucidated.

Graphical abstract: Modulation of (non)linear optical properties in tripodal molecules by variation of the peripheral cyano acceptor moieties and the π-spacer

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Publication details

The article was received on 07 May 2015, accepted on 12 Jun 2015 and first published on 16 Jun 2015


Article type: Paper
DOI: 10.1039/C5TC01293G
Citation: J. Mater. Chem. C, 2015,3, 7345-7355
  • Open access: Creative Commons BY-NC license
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    Modulation of (non)linear optical properties in tripodal molecules by variation of the peripheral cyano acceptor moieties and the π-spacer

    D. Cvejn, E. Michail, I. Polyzos, N. Almonasy, O. Pytela, M. Klikar, T. Mikysek, V. Giannetas, M. Fakis and F. Bureš, J. Mater. Chem. C, 2015, 3, 7345
    DOI: 10.1039/C5TC01293G

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