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Issue 14, 2015
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Pd-catalyzed asymmetric allylic amination using easily accessible metallocenyl P,N-ligands

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Abstract

Compared to their C1-symmetric counterparts, planar chiral C2-symmetric metallocenyl P,N-ligands are efficient chiral ligands for Pd-catalyzed asymmetric allylic aminations, providing a number of amination products with high enantioselectivities. A non-C2-symmetric ferrocenyl P,N-ligand (a by-product obtained during the synthesis of the above C2-symmetric species) was also found to be an efficient ligand for asymmetric allylic aminations. A mixed ligand system consisting of both C2- and non-C2-symmetric ferrocene complexes was examined and showed high catalytic activity with the amination products being obtained with excellent enantioselectivities.

Graphical abstract: Pd-catalyzed asymmetric allylic amination using easily accessible metallocenyl P,N-ligands

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Publication details

The article was received on 07 Jan 2015, accepted on 23 Feb 2015 and first published on 24 Feb 2015


Article type: Paper
DOI: 10.1039/C5OB00032G
Citation: Org. Biomol. Chem., 2015,13, 4248-4254
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    Pd-catalyzed asymmetric allylic amination using easily accessible metallocenyl P,N-ligands

    H. Wu, F. Xie, Y. Wang, X. Zhao, D. Liu and W. Zhang, Org. Biomol. Chem., 2015, 13, 4248
    DOI: 10.1039/C5OB00032G

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