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Issue 14, 2015
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Oxidative cleavage of allyl ethers by an oxoammonium salt

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Abstract

A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.

Graphical abstract: Oxidative cleavage of allyl ethers by an oxoammonium salt

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Publication details

The article was received on 06 Feb 2015, accepted on 25 Feb 2015 and first published on 25 Feb 2015


Article type: Paper
DOI: 10.1039/C5OB00270B
Citation: Org. Biomol. Chem., 2015,13, 4255-4259
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    Oxidative cleavage of allyl ethers by an oxoammonium salt

    C. B. Kelly, J. M. Ovian, R. M. Cywar, T. R. Gosselin, R. J. Wiles and N. E. Leadbeater, Org. Biomol. Chem., 2015, 13, 4255
    DOI: 10.1039/C5OB00270B

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