Issue 29, 2015
From the journal:

Dalton Transactions

Chiral porous metal–organic frameworks containing μ-oxo-bis[Ti(salan)] units for asymmetric cyanation of aldehydes†

Xia Du,ab   Zijian Li,a   Yan Liu,*a   Shiping Yangb  and  Yong Cui*ac  

* Corresponding authors

a School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
E-mail: liuy@sjtu.edu.cn, yongcui@sjtu.edu.cn
Fax: (+86) 21-5474-1297

b Department of Chemistry, College of Life and Environmental Science, Shanghai Normal University, Shanghai 200234, China

c Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Abstract

Two chiral porous Ti(salan)-based metal–organic frameworks are constructed and are shown to be efficient and recyclable heterogeneous catalysts for asymmetric cyanation reaction of aldehydes, displaying significantly higher enantioselectivity than their homogeneous counterpart.

Graphical abstract: Chiral porous metal–organic frameworks containing μ-oxo-bis[Ti(salan)] units for asymmetric cyanation of aldehydes

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Article information

DOI
https://doi.org/10.1039/C5DT01682G
Article type
Communication
Submitted
04 May 2015
Accepted
23 Jun 2015
First published
24 Jun 2015

Dalton Trans., 2015,44, 12999-13002

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Chiral porous metal–organic frameworks containing μ-oxo-bis[Ti(salan)] units for asymmetric cyanation of aldehydes

X. Du, Z. Li, Y. Liu, S. Yang and Y. Cui, Dalton Trans., 2015, 44, 12999 DOI: 10.1039/C5DT01682G

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