Jump to main content
Jump to site search

Issue 29, 2015
Previous Article Next Article

Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state

Author affiliations

Abstract

Solid [CuI(piperazine)0.5], characterized by a structure with an infinite double chain of CuI, presents an unexpected dual luminescence. The short copper–copper distances allow the existence of both cluster-centered and 1-D delocalized electronic transitions, as emerged from theoretical calculations. Beyond the more common cluster-centered emission a higher energy band, which differs in lifetime and in temperature dependence, is observed.

Graphical abstract: Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state

  • This article is part of the themed collection: HOT Articles
Back to tab navigation

Supplementary files

Publication details

The article was received on 10 Jun 2015, accepted on 24 Jun 2015 and first published on 24 Jun 2015


Article type: Communication
DOI: 10.1039/C5DT02204E
Citation: Dalton Trans., 2015,44, 13003-13006
  •   Request permissions

    Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state

    L. Maini, D. Braga, P. P. Mazzeo, L. Maschio, M. Rérat, I. Manet and B. Ventura, Dalton Trans., 2015, 44, 13003
    DOI: 10.1039/C5DT02204E

Search articles by author

Spotlight

Advertisements