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Issue 69, 2015
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The molecular and electronic structures of a thioaroyl cation formed by borinium ion-mediated C[double bond, length as m-dash]S double bond cleavage of CS2

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Abstract

The first crystallographic and electron density distribution analyses of a thioaroyl cation unveil its true structural perspective; this chemical species can be mainly expressed as the combination of the thioketene form (II) and sulfonium form (III) with a C[triple bond, length as m-dash]S+ triple bond character.

Graphical abstract: The molecular and electronic structures of a thioaroyl cation formed by borinium ion-mediated C [[double bond, length as m-dash]] S double bond cleavage of CS2

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Publication details

The article was received on 08 Jul 2015, accepted on 23 Jul 2015 and first published on 23 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC05645D
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 13342-13345
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    The molecular and electronic structures of a thioaroyl cation formed by borinium ion-mediated C[double bond, length as m-dash]S double bond cleavage of CS2

    Y. Shoji, N. Tanaka, D. Hashizume and T. Fukushima, Chem. Commun., 2015, 51, 13342
    DOI: 10.1039/C5CC05645D

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