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Issue 19, 2015
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Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

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Abstract

Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

Graphical abstract: Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

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Publication details

The article was received on 15 Jan 2015, accepted on 03 Feb 2015 and first published on 03 Feb 2015


Article type: Communication
DOI: 10.1039/C5CC00407A
Citation: Chem. Commun., 2015,51, 4089-4092
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    Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

    S. E. Walker, C. J. C. Lamb, N. A. Beattie, P. Nikodemiak and A.-L. Lee, Chem. Commun., 2015, 51, 4089
    DOI: 10.1039/C5CC00407A

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