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Issue 41, 2014
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Self-assembly of hard helices: a rich and unconventional polymorphism

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Abstract

Hard helices can be regarded as a paradigmatic elementary model for a number of natural and synthetic soft matter systems, all featuring the helix as their basic structural unit, from natural polynucleotides and polypeptides to synthetic helical polymers, and from bacterial flagella to colloidal helices. Here we present an extensive investigation of the phase diagram of hard helices using a variety of methods. Isobaric Monte Carlo numerical simulations are used to trace the phase diagram; on going from the low-density isotropic to the high-density compact phases a rich polymorphism is observed, exhibiting a special chiral screw-like nematic phase and a number of chiral and/or polar smectic phases. We present full characterization of the latter, showing that they have unconventional features, ascribable to the helical shape of the constituent particles. Equal area construction is used to locate the isotropic-to-nematic phase transition, and the results are compared with those stemming from an Onsager-like theory. Density functional theory is also used to study the nematic-to-screw-nematic phase transition; within the simplifying assumption of perfectly parallel helices, we compare different levels of approximation, that is second- and third-virial expansions and a Parsons–Lee correction.

Graphical abstract: Self-assembly of hard helices: a rich and unconventional polymorphism

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Publication details

The article was received on 17 Jun 2014, accepted on 31 Jul 2014 and first published on 01 Aug 2014


Article type: Paper
DOI: 10.1039/C4SM01305K
Author version available: Download Author version (PDF)
Citation: Soft Matter, 2014,10, 8171-8187
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    Self-assembly of hard helices: a rich and unconventional polymorphism

    H. B. Kolli, E. Frezza, G. Cinacchi, A. Ferrarini, A. Giacometti, T. S. Hudson, C. De Michele and F. Sciortino, Soft Matter, 2014, 10, 8171
    DOI: 10.1039/C4SM01305K

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