Issue 10, 2014
From the journal:

Organic Chemistry Frontiers

Synthesis of benzofurans via ruthenium-catalyzed redox-neutral C–H functionalization and reaction with alkynes under mild conditions†

Zhi Zhou,a   Guixia Liu,*a   Yangyang Shena  and  Xiyan Lu*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, P. R. China
E-mail: guixia@sioc.ac.cn, xylu@mail.sioc.ac.cn

Abstract

Using an oxidizing directing group, a mild RuII-catalyzed direct coupling of N-phenoxypivalamide with internal alkynes was developed, generating the benzofurans in moderate to high yields.

Graphical abstract: Synthesis of benzofurans via ruthenium-catalyzed redox-neutral C–H functionalization and reaction with alkynes under mild conditions

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Article information

DOI
https://doi.org/10.1039/C4QO00196F
Article type
Research Article
Submitted
14 Jul 2014
Accepted
15 Sep 2014
First published
16 Sep 2014

Org. Chem. Front., 2014,1, 1161-1165

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Synthesis of benzofurans via ruthenium-catalyzed redox-neutral C–H functionalization and reaction with alkynes under mild conditions

Z. Zhou, G. Liu, Y. Shen and X. Lu, Org. Chem. Front., 2014, 1, 1161 DOI: 10.1039/C4QO00196F

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