Issue 7, 2014

Intermolecular reactions of gold(i)-carbenes with furans by related mechanisms

Abstract

The intermolecular gold(I)-catalyzed reactions of propargyl carboxylates, 1,6-enynes, or 7-substituted 1,3,5-cycloheptatrienes with furans afford cyclopentenones, polyenes or polycyclic compounds by related mechanisms initiated by the electrophilic addition of gold(I) carbenes to furans followed by ring-opening.

Graphical abstract: Intermolecular reactions of gold(i)-carbenes with furans by related mechanisms

Supplementary files

Article information

Article type
Research Article
Submitted
01 May 2014
Accepted
18 Jun 2014
First published
19 Jun 2014
This article is Open Access
Creative Commons BY license

Org. Chem. Front., 2014,1, 759-764

Author version available

Intermolecular reactions of gold(I)-carbenes with furans by related mechanisms

D. Lebœuf, M. Gaydou, Y. Wang and A. M. Echavarren, Org. Chem. Front., 2014, 1, 759 DOI: 10.1039/C4QO00130C

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