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Issue 7, 2014
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Bi(OTf)3-catalysed synthesis of substituted indanes by a double hydroarylation of unactivated 1,3-dienes

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Abstract

The intermolecular reaction between differently substituted electron-rich arenes and unactivated 1,3-dienes catalysed by bismuth(III) triflate is presented. This highly atom-economical process is conducted under very mild conditions and leads efficiently to substituted indane derivatives through a tandem bis-hydroarylation.

Graphical abstract: Bi(OTf)3-catalysed synthesis of substituted indanes by a double hydroarylation of unactivated 1,3-dienes

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The article was received on 19 May 2014, accepted on 09 Jul 2014 and first published on 10 Jul 2014


Article type: Research Article
DOI: 10.1039/C4QO00149D
Author version available: Download Author version (PDF)
Citation: Org. Chem. Front., 2014,1, 765-769
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    Bi(OTf)3-catalysed synthesis of substituted indanes by a double hydroarylation of unactivated 1,3-dienes

    B. Cacciuttolo, P. Ondet, S. Poulain-Martini, G. Lemière and E. Duñach, Org. Chem. Front., 2014, 1, 765
    DOI: 10.1039/C4QO00149D

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