Issue 28, 2014
From the journal:

Dalton Transactions

Self-assembly of an all-thiol-stabilized {Ag28S23} high-nuclearity luminescent nanocluster with a “crab-like” shape†

Kun Zhou,a   Chao Qin,a   Xin-Long Wang,*a   Kui-Zhan Shao,a   Li-Kai Yana  and  Zhong-Min Su*a  

* Corresponding authors

a Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, China
E-mail: zmsu@nenu.edu.cn
Fax: (+86) 431-85684009
Tel: (+86) 431-85099108

Abstract

We report a rare all-thiol-stabilized [Ag28(StBu)23]5+ ({Ag28S23} for short) nanocluster with a “crab-like” shape in compound [Ag28(StBu)23](CF3COO)5·8CH3OH (1), which has been synthesized by the self-assembly of AgStBu with CF3COOH, Et3N and KBr/KI in methanol. The diffuse reflection spectrum and luminescence spectra of 1 were investigated.

Graphical abstract: Self-assembly of an all-thiol-stabilized {Ag28S23} high-nuclearity luminescent nanocluster with a “crab-like” shape

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4DT00762J
Article type
Communication
Submitted
13 Mar 2014
Accepted
16 Apr 2014
First published
17 Apr 2014

Dalton Trans., 2014,43, 10695-10699

Permissions

Request permissions

Self-assembly of an all-thiol-stabilized {Ag28S23} high-nuclearity luminescent nanocluster with a “crab-like” shape

K. Zhou, C. Qin, X. Wang, K. Shao, L. Yan and Z. Su, Dalton Trans., 2014, 43, 10695 DOI: 10.1039/C4DT00762J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements