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Issue 28, 2014
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A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks

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Abstract

The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [MnIII12] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.

Graphical abstract: A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks

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Publication details

The article was received on 07 Feb 2014, accepted on 22 May 2014 and first published on 22 May 2014


Article type: Communication
DOI: 10.1039/C4DT01469C
Citation: Dalton Trans., 2014,43, 10690-10694
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    A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks

    J. M. Frost, S. Sanz, T. Rajeshkumar, M. B. Pitak, S. J. Coles, G. Rajaraman, W. Wernsdorfer, J. Schnack, P. J. Lusby and E. K. Brechin, Dalton Trans., 2014, 43, 10690
    DOI: 10.1039/C4DT01469C

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