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Issue 51, 2012
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Exploiting a novel size exclusion phenomenon for enantioselective acid/base cascade catalysis

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Abstract

A novel size exclusion phenomenon between PS-BEMP and sterically bulky BPAs, has been discovered and exploited in a one-pot base-catalysed Michael addition/acid-catalysed enantioselective N-acyliminium cyclisation cascade, allowing the preparation of structurally complex β-carbolines with moderate to good enantiocontrol.

Graphical abstract: Exploiting a novel size exclusion phenomenon for enantioselective acid/base cascade catalysis

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Publication details

The article was received on 28 Mar 2012, accepted on 27 Apr 2012 and first published on 23 May 2012


Article type: Communication
DOI: 10.1039/C2CC32258G
Citation: Chem. Commun., 2012,48, 6351-6353
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    Exploiting a novel size exclusion phenomenon for enantioselective acid/base cascade catalysis

    M. E. Muratore, L. Shi<small xmlns="http://www.rsc.org/schema/rscart38"> <sup /> </small>, A. W. Pilling, R. I. Storer and D. J. Dixon, Chem. Commun., 2012, 48, 6351
    DOI: 10.1039/C2CC32258G

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