Issue 38, 2011
From the journal:

Chemical Communications

Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate†

Mathieu Ratel,a   Mathieu Branca,a   Julien Breault-Turcot,a   Sandy Shuo Zhao,a   Pierre Chaurand,a   Andreea R. Schmitzer*a  and  Jean-Francois Masson*a  

* Corresponding authors

a Department of Chemistry, Université de Montréal, C.P. 6128 Succ. Centre-Ville, Montréal, QC, Canada
E-mail: jf.masson@umontreal.ca, ar.schmitzer@umontreal.ca
Fax: +1-514-343-7586
Tel: +1-514-343-7342

Abstract

A simple anion metathesis in diluted aqueous carbonate at room temperature affords 1-(12-mercaptododecyl)-3-methyl-imidazolium carbonate (MDMI-HCO3) from MDMI salts self-assembled on gold films and nanoparticles. The properties of MDMI-SAM differ from MDMI in solution, for which the anion exchange reaction does not proceed.

Graphical abstract: Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate

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Article information

DOI
https://doi.org/10.1039/C1CC13914B
Article type
Communication
Submitted
30 Jun 2011
Accepted
15 Aug 2011
First published
30 Aug 2011

Chem. Commun., 2011,47, 10644-10646

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Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate

M. Ratel, M. Branca, J. Breault-Turcot, S. S. Zhao, P. Chaurand, A. R. Schmitzer and J. Masson, Chem. Commun., 2011, 47, 10644 DOI: 10.1039/C1CC13914B

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