Issue 22, 2006

Application of the semi-pinacol rearrangement towards the generation of alkenyl-substituted quaternary carbon centres

Abstract

The semi-pinacol rearrangement has been carried out on 2-methyl-2,3-epoxy-cyclopentanone derivatives, generating alkenyl-substituted quaternary carbon centred aldols with a defined relative stereochemistry.

Graphical abstract: Application of the semi-pinacol rearrangement towards the generation of alkenyl-substituted quaternary carbon centres

Article information

Article type
Paper
Submitted
18 Aug 2006
Accepted
19 Sep 2006
First published
05 Oct 2006

Org. Biomol. Chem., 2006,4, 4144-4148

Application of the semi-pinacol rearrangement towards the generation of alkenyl-substituted quaternary carbon centres

T. J. Snape, Org. Biomol. Chem., 2006, 4, 4144 DOI: 10.1039/B611912C

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