Issue 5, 2003
From the journal:

Dalton Transactions

Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions†

Emmanuel Terazzi,a   Jean-Marc Bénech,a   Jean-Pierre Rivera,a   Gérald Bernardinelli,b   Bertrand Donnio,c   Daniel Guillonc  and  Claude Piguet*a  

* Corresponding authors

a Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai E. Ansermet, CH-1211 Geneva 4, Switzerland
E-mail: Claude.Piguet@chiam.unige.ch

b Laboratory of X-ray crystallography, University of Geneva, 24 quai E. Ansermet, CH-1211 Geneva 4, Switzerland

c Institut de Physique et de Chimie des Matériaux de Strasbourg, Groupe des Matériaux Organiques, 23 rue du Loess, F-67037 Strasbourg Cedex, France

Abstract

The increase of the curvature of the interface between the rigid mesogenic core and the aliphatic chains in the hexacatenar tridentate ligand L3 overcomes the considerable expansion brought by the complexation of bulky metallic cores, thus leading to organized cubic mesophases for monometallic zincII and lanthanideIII complexes.

Graphical abstract: Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions

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Article information

DOI
https://doi.org/10.1039/B211902A
Article type
Communication
Submitted
04 Dec 2002
Accepted
24 Jan 2003
First published
03 Feb 2003

Dalton Trans., 2003, 769-772

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Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions

E. Terazzi, J. Bénech, J. Rivera, G. Bernardinelli, B. Donnio, D. Guillon and C. Piguet, Dalton Trans., 2003, 769 DOI: 10.1039/B211902A

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