Issue 1, 2000
From the journal:

Chemical Communications

Self assembly of a novel water soluble iron(ii) macrocyclic phosphine complex from tetrakis(hydroxymethyl)phosphonium sulfate and iron(ii) ammonium sulfate: single crystal X-ray structure of the complex [Fe(H2O)2{RP(CH2N(CH2PR 2)CH2)2PR}]SO4·4H 2O (R = CH2OH)

John C. Jeffery,*a   Barbara Odell,*b   Nicola Stevens*c  and  Robert E. Talbot*c  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantocks Close, Bristol, UK
E-mail: john.jeffery@bristol.ac.uk

b Dyson Perrins Laboratory, University of Oxford, South Parks Road, Oxford, UK
E-mail: barbara.odell@chemistry.oxford.ac.uk

c Albright and Wilson UK Ltd., PO Box 80, Trinity Street, Oldbury, West Midlands, UK
E-mail: bob_e_talbot@albriw.com

Abstract

The water soluble Fe(II) macrocyclic phosphine complex [Fe(H2O)2{RP(CH2N(CH2PR 2)CH2)2PR}]SO4·4H 2O (R = CH2OH) has been characterised by single crystal X-ray diffraction and is formed by a remarkable self-assembly reaction between iron(II) ammonium sulfate and tetrakis(hydroxymethyl)phosphonium sulfate (THPS).

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Article information

DOI
https://doi.org/10.1039/A908309J
Article type
Communication
Submitted
18 Oct 1999
Accepted
06 Dec 1999
First published
06 Jan 2000

Chem. Commun., 2000, 101-102

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Self assembly of a novel water soluble iron(II) macrocyclic phosphine complex from tetrakis(hydroxymethyl)phosphonium sulfate and iron(II) ammonium sulfate: single crystal X-ray structure of the complex [Fe(H2O)2{RP(CH2N(CH2PR 2)CH2)2PR}]SO4·4H 2O (R = CH2OH)

J. C. Jeffery, B. Odell, N. Stevens and R. E. Talbot, Chem. Commun., 2000, 101 DOI: 10.1039/A908309J

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