An electron rich dihydrobenzoxazine based α-amino acid has been synthesized using the Schollkopf chiral auxiliary giving a new adaptation of the standard Cα–Cβ bond formation strategy, as required by the electron rich nature of the side chain.
S. Kotha and A. Kuki, J. Chem. Soc., Chem. Commun., 1992, 404 DOI: 10.1039/C39920000404
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