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Issue 41, 2015
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Visible-light-promoted chloramination of olefins with N-chlorosulfonamide as both nitrogen and chlorine sources

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Abstract

A visible-light-promoted chloramination of olefins is reported. N-Chlorosulfonamides serve as both nitrogen and chlorine sources. These reactions provide a simple, efficient, regioselective, and atom-economical method for the preparation of vicinal haloamine derivatives under mild reaction conditions. A variety of olefins were tolerated, and chloramination products were obtained in good yields.

Graphical abstract: Visible-light-promoted chloramination of olefins with N-chlorosulfonamide as both nitrogen and chlorine sources

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Publication details

The article was received on 17 Aug 2015, accepted on 18 Sep 2015 and first published on 21 Sep 2015


Article type: Communication
DOI: 10.1039/C5OB01725D
Author version available: Download Author version (PDF)
Citation: Org. Biomol. Chem., 2015,13, 10295-10298
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    Visible-light-promoted chloramination of olefins with N-chlorosulfonamide as both nitrogen and chlorine sources

    Q. Qin, D. Ren and S. Yu, Org. Biomol. Chem., 2015, 13, 10295
    DOI: 10.1039/C5OB01725D

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