Aluminium hydride        nanoparticles nested in the porous zeolitic imidazolate framework-8

Ewa M. Banach; Hans A. Stil; Hans Geerlings

doi:10.1039/C1JM13343H

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Aluminium hydridenanoparticles nested in the porous zeolitic imidazolate framework-8†

Ewa M. Banach,*^a Hans A. Stil^a and Hans Geerlings^ab

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* Corresponding authors

^a Shell Global Solutions International B.V., Grasweg 31, Amsterdam, The Netherlands
E-mail: ewa.banach@shell.com
Fax: +31 206303964
Tel: +31 206303460

^b Delft University of Technology, Faculty of Applied Sciences, Department of Chemical Engineering, P.O. Box 5045, Delft, The Netherlands

Abstract

Aluminium hydride particles were loaded for the first time in a ZIF-8 structure by the solution infiltration method using dimethylethylamine alane [AlH₃:NMe₂Et] as a precursor. The infiltrated aluminium hydride is present within ZIF-8 pores preserving the zeolitic structure, as shown by various advanced analytical techniques.

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Article information

DOI: https://doi.org/10.1039/C1JM13343H
Article type: Communication
Submitted: 15 Jul 2011
Accepted: 01 Nov 2011
First published: 14 Nov 2011

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J. Mater. Chem., 2012,22, 324-327

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Aluminium hydride nanoparticles nested in the porous zeolitic imidazolate framework-8

E. M. Banach, H. A. Stil and H. Geerlings, J. Mater. Chem., 2012, 22, 324 DOI: 10.1039/C1JM13343H

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Journal of Materials Chemistry