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Issue 2, 2012
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Poly(ionic liquid) and macrocyclic polyoxometalate ionic self-assemblies: new water-insoluble and visible light photosensitive catalysts

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Abstract

Several poly(ionic liquid)s (PILs) were synthesized and assembled with a multielectronic-process sustaining polyoxometalate (POM) into new green and water-insoluble nanomaterials (POM@PILs). They are visible light photosensitive, unlike their two components. A synergic effect was highlighted for the first time. POM@PILs achieve complete photodegradation of AO7 in aerobic media. The photocatalysts were recoverable and recyclable.

Graphical abstract: Poly(ionic liquid) and macrocyclic polyoxometalate ionic self-assemblies: new water-insoluble and visible light photosensitive catalysts

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Publication details

The article was received on 14 Sep 2011, accepted on 03 Oct 2011 and first published on 26 Oct 2011


Article type: Communication
DOI: 10.1039/C1JM14573H
Citation: J. Mater. Chem., 2012,22, 319-323
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    Poly(ionic liquid) and macrocyclic polyoxometalate ionic self-assemblies: new water-insoluble and visible light photosensitive catalysts

    R. N. Biboum, F. Doungmene, B. Keita, P. de Oliveira, L. Nadjo, B. Lepoittevin, P. Roger, F. Brisset, P. Mialane, A. Dolbecq, I. M. Mbomekalle, C. Pichon, P. Yin, T. Liu and R. Contant, J. Mater. Chem., 2012, 22, 319
    DOI: 10.1039/C1JM14573H

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