Issue 1, 2007
From the journal:

Green Chemistry

Novel modified soybean oil containing hydrazino-ester: synthesis and characterization

Atanu Biswas,*a   Brajendra K. Sharma,bc   J. L. Willet,a   K. Vermillion,d   Sevim Z. Erhanb  and  H. N. Cheng*e  

* Corresponding authors

a Plant Polymer Research Unit, National Center for Agricultural Utilization Research, USDA/Agricultural Research Services, 1815 N. University Street, Peoria, IL, USA

b Food and Industrial Oil Research Unit, National Center for Agricultural Utilization Research, USDA/Agricultural Research Services, 1815 N. University Street, Peoria, IL, USA

c Department of Chemical Engineering, Pennsylvania State University, University Park, PA, USA

d New Crops and Processing Technology Research Unit, National Center for Agricultural Utilization Research, USDA/Agricultural Research Services, 1815 N. University Street, Peoria, IL, USA

e Hercules Incorporated Research Center, 500 Hercules Road, Wilmington, DE, USA

Abstract

A novel synthetic approach for chemical modification of vegetable oils is presented. The structural modification is carried out using diethyl azodicarboxylate (DEAD) in the absence of catalyst and solvent. In a microwave oven the reaction can be achieved in 5–15 minutes. The reaction can also proceed using conventional heat, albeit for a longer time. The products are characterized by 1H, 13C, and two-dimensional NMR.

Graphical abstract: Novel modified soybean oil containing hydrazino-ester: synthesis and characterization

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Article information

DOI
https://doi.org/10.1039/B608075H
Article type
Paper
Submitted
07 Jun 2006
Accepted
18 Oct 2006
First published
31 Oct 2006

Green Chem., 2007,9, 85-89

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Novel modified soybean oil containing hydrazino-ester: synthesis and characterization

A. Biswas, B. K. Sharma, J. L. Willet, K. Vermillion, S. Z. Erhan and H. N. Cheng, Green Chem., 2007, 9, 85 DOI: 10.1039/B608075H

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