Reversing the relative 3MLCT–3MC order in Fe(ii) complexes using cyclometallating ligands: a computational study aiming at luminescent Fe(ii) complexes

Abstract

Following a computational approach, the use of strongly electron-donating cyclometallating ligands has allowed us to increase the ³MC–³MLCT gap dramatically in Fe(II) bis(tridentate) polypyridine complexes, and eventually to reverse the ordering between these states, yielding a ³MLCT state that is clearly more stable than the ³MC state. Simultaneously, the quintet excited states (⁵MC and ⁵MLCT) are displaced away from the region (in terms of geometry and energy) where classical photophysics occur, allowing us to avoid magnetism. The situation is thus similar to that of classical ruthenium polypyridine complexes. This opens the way towards luminescent iron(II) complexes, in particular Fe(II)bis(6-phenyl-2,2′-bipyridine) Fe(NNC)₂.