Issue 26, 2012

Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

Abstract

Three synthetic routes to the unusual supramolecular complex ([Cp2Co]2[{(OC)5V}2(μ-1,4-CNC6Me4NC)]), which was crystallographically characterized, are presented. The dianion [{(OC)5V}2(μ-1,4-CNC6Me4NC)]2− constitutes the first subvalent organometallics featuring a diisocyanoarene linker.

Graphical abstract: Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

Supplementary files

Article information

Article type
Communication
Submitted
29 Feb 2012
Accepted
02 Apr 2012
First published
05 Apr 2012

Dalton Trans., 2012,41, 7845-7848

Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

T. R. Maher, J. J. Meyers, A. D. Spaeth, K. R. Lemley and M. V. Barybin, Dalton Trans., 2012, 41, 7845 DOI: 10.1039/C2DT30488K

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