Issue 26, 2012

Convenient C-alkylation of the [HCB11Cl11]carborane anion

Abstract

A method for C-alkylation of [HCB11Cl11] anions using potassium tert-butoxide and alkyl iodides in tert-butanol is presented. Trimethylammonium salts of the corresponding C-alkylated derivatives are easily isolated and obtained in good yields.

Graphical abstract: Convenient C-alkylation of the [HCB11Cl11]− carborane anion

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
16 Dec 2011
Accepted
08 Feb 2012
First published
09 Mar 2012

Dalton Trans., 2012,41, 7842-7844

Convenient C-alkylation of the [HCB11Cl11] carborane anion

R. Ramírez-Contreras and O. V. Ozerov, Dalton Trans., 2012, 41, 7842 DOI: 10.1039/C2DT12431A

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