Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

Tiffany R. Maher; John J. Meyers; Andrew D. Spaeth; Krista R. Lemley; Mikhail V. Barybin

doi:10.1039/C2DT30488K

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Dalton Transactions

Issue 26, 2012

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

Tiffany R. Maher,^a John J. Meyers,^a Andrew D. Spaeth,^a Krista R. Lemley^a and Mikhail V. Barybin*^a

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Department of Chemistry, The University of Kansas, 1251 Wescoe Hall Drive, Lawrence, USA
E-mail: mbarybin@ku.edu ;
Fax: +1-785-864-5396 ;
Tel: +1-785-864-4106

Dalton Trans., 2012,41, 7845-7848

DOI: 10.1039/C2DT30488K
Received 29 Feb 2012, Accepted 02 Apr 2012
First published online 05 Apr 2012

This article is part of themed collection: New Talent: Americas

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Abstract
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Three synthetic routes to the unusual supramolecular complex ([Cp₂Co]₂[{(OC)₅V}₂(μ-1,4-CNC₆Me₄NC)])_∞, which was crystallographically characterized, are presented. The dianion [{(OC)₅V}₂(μ-1,4-CNC₆Me₄NC)]²⁻ constitutes the first subvalent organometallics featuring a diisocyanoarene linker.

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Tiffany R. Maher
John J. Meyers
Andrew D. Spaeth
Krista R. Lemley
Mikhail V. Barybin

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Dalton Transactions

Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

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Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

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