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Issue 26, 2012
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Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

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Abstract

Three synthetic routes to the unusual supramolecular complex ([Cp2Co]2[{(OC)5V}2(μ-1,4-CNC6Me4NC)]), which was crystallographically characterized, are presented. The dianion [{(OC)5V}2(μ-1,4-CNC6Me4NC)]2− constitutes the first subvalent organometallics featuring a diisocyanoarene linker.

Graphical abstract: Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

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Publication details

The article was received on 29 Feb 2012, accepted on 02 Apr 2012 and first published on 05 Apr 2012


Article type: Communication
DOI: 10.1039/C2DT30488K
Citation: Dalton Trans., 2012,41, 7845-7848
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    Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

    T. R. Maher, J. J. Meyers, A. D. Spaeth, K. R. Lemley and M. V. Barybin, Dalton Trans., 2012, 41, 7845
    DOI: 10.1039/C2DT30488K

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