Issue 12, 2011
From the journal:

Dalton Transactions

New high-nuclearity manganese clusters containing mixed chelating ligands: Syntheses, crystal structures and magnetochemical characterization†

Hui-Sheng Wang,a   Zai-Chao Zhang,b   Xiao-Jiao Song,a   Jing-Wei Zhang,a   Hong-Bo Zhou,a   Jun Wang,a   You Song*a  and  Xiao-Zeng You*a  

* Corresponding authors

a State Key Laboratory of Coordinate Chemistry, School of Chemistry and Chemical Engineering, Nanjing Nantional Laboratory of Microstructures, Nanjing University, P. R. China
E-mail: songyou@nju.edu.cn, youxz@nju.edu.cn

b Jiangsu Key Laboratory for the Chemistry of Low-dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, P. R. China

Abstract

Two polynuclear mixed-valence manganese clusters, [Mn13] and [Mn16], containing mixed chelating ligands were synthesized and structurally characterized. The alternating current (AC) susceptibilities of both complexes reveal nonzero frequency-dependent out-of-phase (χM′′) signals.

Graphical abstract: New high-nuclearity manganese clusters containing mixed chelating ligands: Syntheses, crystal structures and magnetochemical characterization

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Article information

DOI
https://doi.org/10.1039/C0DT01588A
Article type
Communication
Submitted
16 Nov 2010
Accepted
21 Jan 2011
First published
09 Feb 2011

Dalton Trans., 2011,40, 2703-2706

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New high-nuclearity manganese clusters containing mixed chelating ligands: Syntheses, crystal structures and magnetochemical characterization

H. Wang, Z. Zhang, X. Song, J. Zhang, H. Zhou, J. Wang, Y. Song and X. You, Dalton Trans., 2011, 40, 2703 DOI: 10.1039/C0DT01588A

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