Issue 12, 2011
From the journal:

Dalton Transactions

Synthesis and structural studies of an electron deficient hexatitanium cluster dication stabilized by novel tritin anions†

Neetu Singha  and  Subrato Bhattacharya*a  

* Corresponding authors

a Department of Chemistry, Banaras Hindu University, Varanasi, 221005 India
E-mail: s_bhatt@bhu.ac.in

Abstract

A reaction of Cp2Ti(SH)2 with n-BuSnCl(OH)2 gave two unusual ionic compounds; the cation in both is a hexatitanium cluster, [Cp6Ti6O8]2+, while the anion is a six membered cyclic (chair form) [n-Bu3Sn3Cl(SH)3(S)3]− in one and acyclic [n-Bu3Sn3Cl3(SH)3(S)2]− in the other. Besides X-ray crystallography, theoretical studies have also been completed to understand the structures of these complexes.

Graphical abstract: Synthesis and structural studies of an electron deficient hexatitanium cluster dication stabilized by novel tritin anions

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Article information

DOI
https://doi.org/10.1039/C0DT01353F
Article type
Communication
Submitted
07 Oct 2010
Accepted
25 Jan 2011
First published
18 Feb 2011

Dalton Trans., 2011,40, 2707-2710

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Synthesis and structural studies of an electron deficient hexatitanium cluster dication stabilized by novel tritin anions

N. Singh and S. Bhattacharya, Dalton Trans., 2011, 40, 2707 DOI: 10.1039/C0DT01353F

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