Issue 1, 1993

Proton-coupled electron-transfer reactions. Observation of a reversible OsIV(amide)–OsIII(amine) redox couple with 2,3-diamino-2,3-dimethylbutane

Abstract

The complex trans-[OsIII(L)2Cl2]+(L = 2,3-diamino-2,3-dimethylbutane) is the first to display a reversible pH-dependent OsIV(amide)–OsIII(amine) couple in aqueous solution.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 197-198

Proton-coupled electron-transfer reactions. Observation of a reversible OsIV(amide)–OsIII(amine) redox couple with 2,3-diamino-2,3-dimethylbutane

K. Chin, K. Wong and C. Che, J. Chem. Soc., Dalton Trans., 1993, 197 DOI: 10.1039/DT9930000197

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