Issue 26, 2016
From the journal:

Chemical Communications

Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction†

Tatsuya Kitagawa,a   Junpei Nishino,a   Tomohiko Inomata,*b   Tomohiro Ozawa,a   Yasuhiro Funahashic  and  Hideki Masuda*ad  

* Corresponding authors

a Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Japan

b Department of Material Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology, Japan
E-mail: tino@nitech.ac.jp
Fax: +81 52 735 5673
Tel: +81 52 735 5673

c Department of Chemistry, Graduate School of Science, Osaka University, 1-1, Machikaneyama, Toyonaka, Osaka 560-0043, Japan

d Department of Applied Chemistry, Aichi Institute of Technology, 1247 Yakusa, Yakusa-cho, Toyota 470-0392, Japan

Abstract

An unstable diiron(II,II) complex possessing O2 binding ability at low temperature was encapsulated and stabilized in an ammonium-type ionic liquid layer polymerized on an electrode. The encapsulated complex revealed catalytic reactivity for four-electron reduction of O2 at an ambient temperature in aqueous solution.

Graphical abstract: Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

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Article information

DOI
https://doi.org/10.1039/C5CC10263D
Article type
Communication
Submitted
14 Dec 2015
Accepted
19 Feb 2016
First published
01 Mar 2016

Chem. Commun., 2016,52, 4780-4783

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Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

T. Kitagawa, J. Nishino, T. Inomata, T. Ozawa, Y. Funahashi and H. Masuda, Chem. Commun., 2016, 52, 4780 DOI: 10.1039/C5CC10263D

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