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Issue 26, 2016
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The design of a bipodal bis(pentafluorophenoxy)aluminate supported on silica as an activator for ethylene polymerization using surface organometallic chemistry

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Abstract

A new class of well-defined activating supports for olefin polymerization was obtained via the surface organometallic chemistry approach. High activities in slurry polymerization of ethylene along with industrial-grade physical properties of the resulting polyethylene were obtained when these activators were combined with metallocene complexes in the presence of triisobutylaluminium.

Graphical abstract: The design of a bipodal bis(pentafluorophenoxy)aluminate supported on silica as an activator for ethylene polymerization using surface organometallic chemistry

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Publication details

The article was received on 04 Jan 2016, accepted on 15 Feb 2016 and first published on 15 Feb 2016


Article type: Communication
DOI: 10.1039/C6CC00060F
Citation: Chem. Commun., 2016,52, 4776-4779
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    The design of a bipodal bis(pentafluorophenoxy)aluminate supported on silica as an activator for ethylene polymerization using surface organometallic chemistry

    D. W. Sauter, N. Popoff, M. A. Bashir, K. C. Szeto, R. M. Gauvin, L. Delevoye, M. Taoufik and C. Boisson, Chem. Commun., 2016, 52, 4776
    DOI: 10.1039/C6CC00060F

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