Issue 66, 2015

Mononuclear nonheme iron(iv)–oxo and manganese(iv)–oxo complexes in oxidation reactions: experimental results prove theoretical prediction

Abstract

Reactivities of mononuclear nonheme iron(IV)–oxo and manganese(IV)–oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that FeIVO is more reactive than MnIVO. The latter is shown to react through excited state reactivity (ESR).

Graphical abstract: Mononuclear nonheme iron(iv)–oxo and manganese(iv)–oxo complexes in oxidation reactions: experimental results prove theoretical prediction

Supplementary files

Article information

Article type
Communication
Submitted
21 May 2015
Accepted
05 Jul 2015
First published
06 Jul 2015

Chem. Commun., 2015,51, 13094-13097

Mononuclear nonheme iron(IV)–oxo and manganese(IV)–oxo complexes in oxidation reactions: experimental results prove theoretical prediction

J. Chen, K. Cho, Y. Lee, Y. H. Kwon and W. Nam, Chem. Commun., 2015, 51, 13094 DOI: 10.1039/C5CC04217H

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