Issue 79, 2014
From the journal:

Chemical Communications

Storable N-phenylcarbamate palladacycles for rapid functionalization of an alkyne-encoded protein†

Gang Cheng,‡a   Reyna K. V. Lim,a   Carlo P. Ramila  and  Qing Lin*a  

* Corresponding authors

a Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260, USA
E-mail: qinglin@buffalo.edu
Fax: +1 716 6456963
Tel: +1 716 645 4254

Abstract

Here we report the synthesis of storable N-phenylcarbamate palladacycles that showed robust reactivity in the cross-coupling reaction with an alkyne-encoded protein with a second-order rate constant approaching 19 770 ± 930 M−1 s−1.

Graphical abstract: Storable N-phenylcarbamate palladacycles for rapid functionalization of an alkyne-encoded protein

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Article information

DOI
https://doi.org/10.1039/C4CC02969K
Article type
Communication
Submitted
22 Apr 2014
Accepted
08 Aug 2014
First published
08 Aug 2014

Chem. Commun., 2014,50, 11679-11682

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Storable N-phenylcarbamate palladacycles for rapid functionalization of an alkyne-encoded protein

G. Cheng, R. K. V. Lim, C. P. Ramil and Q. Lin, Chem. Commun., 2014, 50, 11679 DOI: 10.1039/C4CC02969K

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