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Issue 79, 2014
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Classical and non-classical redox reactions of Pd(II) complexes containing redox-active ligands

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Abstract

Reactivity studies of a Pd(II)–verdazyl complex reveal novel ligand-centred reduction processes which trigger pseudo-reductive elimination at Pd. Reaction of the complex with water induces a ligand-centred redox disproportionation. The reduced verdazyl ligands can also be reversibly protonated.

Graphical abstract: Classical and non-classical redox reactions of Pd(ii) complexes containing redox-active ligands

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Publication details

The article was received on 26 Jun 2014, accepted on 06 Aug 2014 and first published on 08 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC04863F
Citation: Chem. Commun., 2014,50, 11676-11678
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    Classical and non-classical redox reactions of Pd(II) complexes containing redox-active ligands

    C. A. Sanz, M. J. Ferguson, R. McDonald, B. O. Patrick and R. G. Hicks, Chem. Commun., 2014, 50, 11676
    DOI: 10.1039/C4CC04863F

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