Issue 27, 2010

Direct Pd-catalyzed benzylation of highly electron-deficient perfluoroarenes

Abstract

An efficient and practical method to a wide range of perfluorinated unsymmetrical diarylmethanes with good to excellent yields and high regioselectivities has been developed by Pd-catalyzed direct benzylation of highly electron-deficient perfluoroarenes; excellent compatibility of functional groups has also been established.

Graphical abstract: Direct Pd-catalyzed benzylation of highly electron-deficient perfluoroarenes

Supplementary files

Article information

Article type
Communication
Submitted
26 Mar 2010
Accepted
12 May 2010
First published
04 Jun 2010

Chem. Commun., 2010,46, 4926-4928

Direct Pd-catalyzed benzylation of highly electron-deficient perfluoroarenes

S. Fan, C. He and X. Zhang, Chem. Commun., 2010, 46, 4926 DOI: 10.1039/C0CC00598C

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