Issue 8, 2005
From the journal:

Chemical Communications

Enantioselective synthesis of homoallylic alcoholsvia a chiral In(iii)–PYBOX complex†

Jun Lu,ab   Mei-Ling Hong,a   Shun-Jun Ji*b  and  Teck-Peng Loh*ab  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543

b Key Lab. of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering of Suzhou University, Suzhou 215006, China
E-mail: chmlohtp@nus.edu.sg
Fax: +65 6779 1691
Tel: +65 6874 7851

Abstract

In the presence of 20 mol% of a chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with aldehydes to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (60–93% ee).

Graphical abstract: Enantioselective synthesis of homoallylic alcohols via a chiral In(iii)–PYBOX complex

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Article information

DOI
https://doi.org/10.1039/B415550E
Article type
Communication
Submitted
07 Oct 2004
Accepted
16 Nov 2004
First published
05 Jan 2005

Chem. Commun., 2005, 1010-1012

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Enantioselective synthesis of homoallylic alcohols via a chiral In(III)–PYBOX complex

J. Lu, M. Hong, S. Ji and T. Loh, Chem. Commun., 2005, 1010 DOI: 10.1039/B415550E

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