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Issue 8, 2005
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Formation of novel anionic gold–tin cluster compounds

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Abstract

A straightforward procedure for the formation of mixed metal Au/Sn clusters is presented: reaction of the heteroborate [SnB11H11]2− with phosphine gold electrophiles gave the clusters [Bu3NH]3[{(Et3P)Au(SnB11H11)}3] and [Bu3MeN]4[{(dppm)Au2(SnB11H11)2}2], which were characterised by X-ray diffraction.

Graphical abstract: Formation of novel anionic gold–tin cluster compounds

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Publication details

The article was received on 28 Oct 2004, accepted on 19 Nov 2004 and first published on 04 Jan 2005


Article type: Communication
DOI: 10.1039/B416472E
Citation: Chem. Commun., 2005,0, 1013-1015
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    Formation of novel anionic gold–tin cluster compounds

    S. Hagen, L. Wesemann and I. Pantenburg, Chem. Commun., 2005, 0, 1013
    DOI: 10.1039/B416472E

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