Issue 17, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

π-Coordination of ortho-benzoquinone: synthesis and structure of [{Ru2(η4-µ2-o-C6H4O2)(CO)4(AsPh3)}2] and [Ru2(η4-µ2-o-C6H4O2)(CO)4(µ2-I)I]

D. Scott Bohle  and  Patricia A. Goodson  

Abstract

The coordination polymer prepared by treating [Ru3(CO)12] with catechol can be cleaved with either a Lewis base or iodine to give products containing η4-ortho-benzoquinone ligands, two of which, [{Ru2(η4-µ2-o-C6H4O2)(CO)4(AsPh3)}2] and [Ru2(η4-µ2-o-C6H4O2)(CO)4(µ2-I)I] are structurally characterized by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39920001205
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1205-1207

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π-Coordination of ortho-benzoquinone: synthesis and structure of [{Ru2(η4-µ2-o-C6H4O2)(CO)4(AsPh3)}2] and [Ru2(η4-µ2-o-C6H4O2)(CO)4(µ2-I)I]

D. S. Bohle and P. A. Goodson, J. Chem. Soc., Chem. Commun., 1992, 1205 DOI: 10.1039/C39920001205

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