Issue 17, 1992

The mechanism of iodine–water oxidation of H-phosphonate diesters

Abstract

Using 18O-labelling the oxidation of 5-tert-butyl-2-hydroxy-1,3,2-dioxaphosphorinane 8 and 9 with iodine-water has been shown to proceed non-stereospecifically, via a mechanism presumed to involve the formation of an iodophosphate intermediate which, under the reaction conditions, epimerises at phosphorus.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1207-1208

The mechanism of iodine–water oxidation of H-phosphonate diesters

P. M. Cullis and M. Lee, J. Chem. Soc., Chem. Commun., 1992, 1207 DOI: 10.1039/C39920001207

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