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Issue 17, 1992
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The mechanism of iodine–water oxidation of H-phosphonate diesters

Abstract

Using 18O-labelling the oxidation of 5-tert-butyl-2-hydroxy-1,3,2-dioxaphosphorinane 8 and 9 with iodine-water has been shown to proceed non-stereospecifically, via a mechanism presumed to involve the formation of an iodophosphate intermediate which, under the reaction conditions, epimerises at phosphorus.

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Article type: Paper
DOI: 10.1039/C39920001207
Citation: J. Chem. Soc., Chem. Commun., 1992,0, 1207-1208
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    The mechanism of iodine–water oxidation of H-phosphonate diesters

    P. M. Cullis and M. Lee, J. Chem. Soc., Chem. Commun., 1992, 0, 1207
    DOI: 10.1039/C39920001207

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