A stereoselective total synthesis of the dasycarpidan alkaloids dasycarpidone 1, dasycarpidol 2 and nordasycarpidone 3 has been achieved from the tetracyclic intermediate 6, the key step being the oxidation of the C-6 methylene group.
J. Bonjoch, N. Casamitjana, J. Gràcia and J. Bosch, J. Chem. Soc., Chem. Commun., 1991, 1687 DOI: 10.1039/C39910001687
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