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Issue 23, 1991
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[NPrn4]2[(ReS4)Cu5I6] and [NEt4]2[(ReS4)Cu3I4]: novel low dimensional solids

Abstract

The compounds [NPrn4]2[(ReS4)Cu5I6]1 and [NEt4]2[(ReS4)Cu3I4]2, containing polymeric heterometallic chains and interesting structural features according to X-ray structure analyses, have been obtained by reaction of CuI with [NPrn4][ReS(S4)2] in dichloromethane 1 or [NEt4][ReS4]2 in acetone; complexes 1 and 2 are examples of a series of compounds which prove the possibility of a stepwise ‘capping’ of the edges of an ReS4 tetrahedron by a Cu(hal/pseudohal)x fragment (x= 1,2).

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Article type: Paper
DOI: 10.1039/C39910001685
Citation: J. Chem. Soc., Chem. Commun., 1991,0, 1685-1687
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    [NPrn4]2[(ReS4)Cu5I6] and [NEt4]2[(ReS4)Cu3I4]: novel low dimensional solids

    A. Müller, E. Krickemeyer, A. Hildebrand, H. Bögge, K. Schneider and M. Lemke, J. Chem. Soc., Chem. Commun., 1991, 0, 1685
    DOI: 10.1039/C39910001685

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