Reaction of Cs2[TcNCl5] with hydrogen peroxide yields the chloronitridoperoxo complex Cs[TcN(O2)2Cl], which has been shown by single-crystal X-ray analysis to have a distorted pentagonal pyramidal co-ordination geometry with the nitrogen atom in the apical position.
J. Baldas, S. F. Colmanet and M. F. Mackay, J. Chem. Soc., Chem. Commun., 1989, 1890 DOI: 10.1039/C39890001890
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