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Issue 24, 1989
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Extended linear metal–metal interactions in an anionic rhodium(I) complex. X-Ray structure of NMe4[Rh(ox)(CO)2](ox = oxalato)

Abstract

The complex NMe4[Rh(ox)(CO)2](2)(ox = oxalato) was prepared from NMe4[Rh(ox)(cod)](1)(cod[double bond, length half m-dash]cyclo-octa-1,5-diene) by bubbling carbon monoxide and, complex (1) was prepared from Rh2Cl2(cod)2, oxalic acid, and NMe4OH; the solid state structure of (2) consists of infinite chains of metal atoms [Rh ⋯ Rh ⋯ Rh 175.01(3)°] with equal rhodium–rhodium distances of 3.243(1)Å, the shortest distance found in a stacked rhodium complex.

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Article type: Paper
DOI: 10.1039/C39890001889
Citation: J. Chem. Soc., Chem. Commun., 1989, 1889-1890
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    Extended linear metal–metal interactions in an anionic rhodium(I) complex. X-Ray structure of NMe4[Rh(ox)(CO)2](ox = oxalato)

    J. Real, J. C. Bayón, F. J. Lahoz and J. A. López, J. Chem. Soc., Chem. Commun., 1989, 1889
    DOI: 10.1039/C39890001889

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