Synthesis of dialuminium substituted cyclopentyl derivatives via the hydroalumination of hex-1-en-5-yne
Abstract
The dihydroalumination of hex-1-en-5-yne in diethyl ether or triethylamine affords 2,α-bis-aluminomethylcyclopentane and 2,α-bis-alumino-3-methylcyclopentene derivatives, respectively.