New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I)

John Bercaw; Giovanni Guastalla; Jack Halpern

doi:10.1039/C29710001594

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Journal of the Chemical Society D: Chemical Communications

Issue 24, 1971

Journal of the Chemical Society D: Chemical Communications was published between 1969 - 1971.

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New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I)

John Bercaw, Giovanni Guastalla and Jack Halpern

J. Chem. Soc. D, 1971, 1594-1595

DOI: 10.1039/C29710001594

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Abstract
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The preparation and characterization of several series of mixed ligand cobalt(I) complexes of the types [Co(CN)₂(CO)₂(PR₃)]^–, [Co(CN)₂(CO)(PR₃)₂]^–, and [Co(CN)(CO)₂(PR₃)₂], prepared by the reactions of tertiary phosphines (PR₃) with [Co(CN)₃(CO)₂]^2–, are described and some novel aspects of their chemistry are discussed.

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New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I)

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Journal of the Chemical Society D: Chemical Communications

New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I)

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