The preparation and characterization of several series of mixed ligand cobalt(I) complexes of the types [Co(CN)2(CO)2(PR3)]–, [Co(CN)2(CO)(PR3)2]–, and [Co(CN)(CO)2(PR3)2], prepared by the reactions of tertiary phosphines (PR3) with [Co(CN)3(CO)2]2–, are described and some novel aspects of their chemistry are discussed.
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Journal of the Chemical Society D: Chemical Communications
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