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Issue 14, 2018
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Radical fluoroalkylthiolation of aldehydes with PhSO2SRf (Rf = CF3, C2F5, CF2H or CH2F): a general protocol for the preparation of fluoroalkylthioesters

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Abstract

A general method for the preparation of fluoroalkylthioesters including trifluoromethylthio/pentafluoroethylthio/difluoromethylthio/monofluoromethylthio-esters from aldehydes and a corresponding fluoroalkylthiolating reagent was reported. The reactions were conducted under mild conditions and various common functional groups such as fluorine, chloride, bromide, iodide, and ester groups were compatible.

Graphical abstract: Radical fluoroalkylthiolation of aldehydes with PhSO2SRf (Rf = CF3, C2F5, CF2H or CH2F): a general protocol for the preparation of fluoroalkylthioesters

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Publication details

The article was received on 30 Mar 2018, accepted on 26 May 2018 and first published on 28 May 2018


Article type: Research Article
DOI: 10.1039/C8QO00327K
Citation: Org. Chem. Front., 2018,5, 2163-2166
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    Radical fluoroalkylthiolation of aldehydes with PhSO2SRf (Rf = CF3, C2F5, CF2H or CH2F): a general protocol for the preparation of fluoroalkylthioesters

    B. Xu, D. Li, L. Lu, D. Wang, Y. Hu and Q. Shen, Org. Chem. Front., 2018, 5, 2163
    DOI: 10.1039/C8QO00327K

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