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Issue 76, 2016
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Enhancement of magnetic anisotropy in a Mn–Bi heterobimetallic complex

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Abstract

A novel Mn2+⋯Bi3+ heterobimetallic complex, featuring the closest Mn⋯Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn2+ to a heavy main group element, namely, bismuth.

Graphical abstract: Enhancement of magnetic anisotropy in a Mn–Bi heterobimetallic complex

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Publication details

The article was received on 01 Aug 2016, accepted on 25 Aug 2016 and first published on 01 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC06369A
Citation: Chem. Commun., 2016,52, 11394-11397
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    Enhancement of magnetic anisotropy in a Mn–Bi heterobimetallic complex

    T. J. Pearson, M. S. Fataftah and D. E. Freedman, Chem. Commun., 2016, 52, 11394
    DOI: 10.1039/C6CC06369A

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