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Issue 79, 2016
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KNH2–KH: a metal amide–hydride solid solution

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Abstract

We report for the first time the formation of a metal amide–hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2 ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.

Graphical abstract: KNH2–KH: a metal amide–hydride solid solution

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Publication details

The article was received on 13 Jul 2016, accepted on 31 Aug 2016 and first published on 31 Aug 2016


Article type: Communication
DOI: 10.1039/C6CC05777B
Citation: Chem. Commun., 2016,52, 11760-11763
  • Open access: Creative Commons BY license
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    KNH2–KH: a metal amide–hydride solid solution

    A. Santoru, C. Pistidda, M. H. Sørby, M. R. Chierotti, S. Garroni, E. Pinatel, F. Karimi, H. Cao, N. Bergemann, T. T. Le, J. Puszkiel, R. Gobetto, M. Baricco, B. C. Hauback, T. Klassen and M. Dornheim, Chem. Commun., 2016, 52, 11760
    DOI: 10.1039/C6CC05777B

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